Polynuclear Hydrocarbons Notes pdf download lecture 2023

Polynuclear Hydrocarbons Notes PDF

Free Polynuclear Hydrocarbons notes pdf are provided here for Polynuclear Hydrocarbons students so that they can prepare and score high marks in their Polynuclear Hydrocarbons exam.

In these free Polynuclear Hydrocarbons notes pdf, we will study the Nitrogen containing functional groups and introduction of polynuclear hydrocarbons, heterocyclic systems, and natural compounds viz. terpenes and alkaloids. A comprehensive understanding of these topics will be developed by taking examples of representative members of each class. The chemical synthesis, properties and reactions of these compounds will be discussed in detail.

We have provided complete Polynuclear Hydrocarbons handwritten notes pdf for any university student of BCA, MCA, B.Sc, B.Tech, M.Tech branch to enhance more knowledge about the subject and to score better marks in their Polynuclear Hydrocarbons exam.

Free Polynuclear Hydrocarbons notes pdf are very useful for Polynuclear Hydrocarbons students in enhancing their preparation and improving their chances of success in Polynuclear Hydrocarbons exam.

These free Polynuclear Hydrocarbons pdf notes will help students tremendously in their preparation for Polynuclear Hydrocarbons exam. Please help your friends in scoring good marks by sharing these free Polynuclear Hydrocarbons handwritten notes pdf from below links:

Topics in our Polynuclear Hydrocarbons Notes PDF

The topics we will cover in these Polynuclear Hydrocarbons Notes pdf will be taken from the following list:

Nitrogen-Containing Functional Groups: Preparation, properties and important reactions of amines and diazonium salts, nitro compounds, nitriles and isonitriles.

A) Amines: Introduction, classification, chirality in amines (pyramidal inversion), importance and general methods of preparation. Properties: Physical properties, Basicity of amines: Effect of substituents, solvent and steric effects. Distinction between Primary, secondary and tertiary amines using Hinsberg’s method and nitrous acid. Discussion of the following reactions with emphasis on the mechanistic pathway: Gabriel Phthalimide synthesis, Hoffmann- Bromamide reaction, Carbylamine reaction, Mannich reaction, Hoffmann’s exhaustive methylation, Hofmann-elimination reaction and Cope elimination.

Diazonium Salts: Preparation and synthetic applications of diazonium salts including preparation of arenes, haloarenes, phenols, cyano and nitro compounds. Coupling reactions of diazonium salts(preparation of azo dyes).

B) Nitro compounds (Aliphatic and Aromatic): Nomenclature, classification and general methods of preparation: from alkyl halides, alkanes, oxidation of amines and oximes and diazonium salts. Properties: Physical properties, discussion on the following reactions with mechanism: Reaction with alkali and its synthetic applications, condensation reaction, Mannich reaction, Hydrolysis,Reduction-electrolytic reduction, reduction in acidic, basic and neutral medium (for aromatic compounds),reaction with nitrous acid, Electrophilic substitution-Halogenation, nitration and sulphonation reaction, and Nucleophilic substitution on the ring.

C) Nitriles: Introduction, Nomenclature and uses. Preparation from the following reactions: Dehydration of amides and aldoximes, substitution reaction in alkyl halides and tosylates, from Grignard reagents and from dehydrogenation of primary amines. Properties: Physical properties, discussion on the following reactions with mechanism: Reaction with Grignard reagent, hydrolysis,addition reaction with HX,NH3,reaction with aqueous ROH, Reduction reactions-catalytic reduction and Stephen’s reaction, Condensation reactions-Thorpe Nitrile Condensation.

D) Isonitriles: Introduction, Nomenclature and uses. Preparation from the following reactions: Carbylamine reaction, substitution in alkyl halides and dehydrogenation of N-substituted formamides. Properties: Physical properties, discussion on the following reactions with mechanism: Hydrolysis, reduction, addition of– HX, X2 and sulphur, Grignard reaction, oxidation and rearrangement.

Polynuclear Hydrocarbons: Introduction, Classification,Structure, Nomenclature and uses. Aromaticity of polynuclear hydrocarbons, structure elucidation of Naphthalene and general methods of preparation of naphthalene, phenanthrene and anthracene(including Haworth method,Friedel Craft acylation, Diels Alder reaction,Elbs reaction and Pschorr Synthesis).Relative reactivity of naphthalene, phenanthrene and anthracene in comparison to benzene. Properties: Physical properties, discussion on the following reaction (with mechanism) for Naphthalene, Anthracene and Phenanthrene: Addition reactions, Oxidation, Electrophilic substitution- Friedel Craft reaction, Chloromethylation, Halogenation, Formylation, Nitration and sulphonation. Reduction reaction and Diels Alder reaction.

Heterocyclic Compounds: Introduction, importance, classification and nomenclature of heterocyclic compounds (containing only one hetero atom). General discussion on the following aspects of heterocyclic compounds: Structure, aromaticity in 5-membered and 6-membered rings containing one heteroatom; Basicity and relative reactivity towards electrophilic substitution reactions(amongst five membered and six membered rings) General methods of synthesis for: Furan, Pyrrole (Paal-Knorr synthesis, Knorr pyrrole synthesis, Hantzsch synthesis), Thiophene, Pyridine (Hantzsch synthesis), Indole(Fischer indole synthesis and Madelung synthesis, reduction of o-nitrobenzaldehyde), Quinoline and isoquinoline, (Skraup synthesis, Friedlander’s synthesis, Knorr quinoline synthesis, Doebner-Miller synthesis, Bischler-Napieralski reaction, Pictet-Spengler reaction, Pomeranz-Fritsch reaction)

Properties: Physical properties, discussion on the following reaction (with mechanism) for Furan, Pyrrole, thiophene, Pyridine, Indole, Quinoline and Isoquinoline: Electrophilic substitution- Nitration, sulphonation, halogenation, Formylation, acylation, mercuration and carboxylation. Oxidation,Reduction, Addition, Reactions showing acidic /basic character.Reaction with diazonium salts, Ring opening, Ring expansion and Nucleophilic substitution reaction wherever applicable should be discussed.

Alkaloids: Introduction, Natural occurrence, Classification, Uses, general structural features, general methods for structure elucidation including Hoffmann’s exhaustive methylation and Emde’s method. Structure elucidation, synthesis and physiological action of Nicotine.

Terpenes: Introduction, Occurrence, Uses, classification, isoprene and special isoprene rule; general methods of structure elucidation including distinction between isopropylidene and isopropenyl group, Elucidation of structure, synthesis and industrial applicationof Citral.

Polynuclear Hydrocarbons Notes PDF FREE Download

Polynuclear Hydrocarbons students can easily make use of all these complete Polynuclear Hydrocarbons notes pdf by downloading them from below links:

How to Download FREE Polynuclear Hydrocarbons Notes PDF?

Polynuclear Hydrocarbons students can easily download free Polynuclear Hydrocarbons notes pdf by following the below steps:

1. Visit TutorialsDuniya.com to download free Polynuclear Hydrocarbons notes pdf
2. Select ‘College Notes’ and then select ‘Chemistry Course’
3. Select ‘Polynuclear Hydrocarbons Notes’
4. Now, you can easily view or download free Polynuclear Hydrocarbons handwritten notes pdf

Benefits of FREE Polynuclear Hydrocarbons Notes PDF

Free Polynuclear Hydrocarbons notes pdf provide learners with a flexible and efficient way to study and reference Polynuclear Hydrocarbons concepts. Benefits of these complete free Polynuclear Hydrocarbons pdf notes are given below:

1. Accessibility: These free Polynuclear Hydrocarbons handwritten notes pdf files can be easily accessed on various devices that makes it convenient for students to study Polynuclear Hydrocarbons wherever they are.
2. Printable: These Polynuclear Hydrocarbons free notes pdf can be printed that allows learners to have physical copies of their Polynuclear Hydrocarbons notes for their reference and offline reading.
3. Structured content: These free Polynuclear Hydrocarbons notes pdf are well-organized with headings, bullet points and formatting that make complex topics easier to follow and understand.
4. Self-Paced Learning: Free Polynuclear Hydrocarbons handwritten notes pdf offers many advantages for both beginners and experienced students that make it a valuable resource for self-paced learning and reference.
5. Visual Elements: These free Polynuclear Hydrocarbons pdf notes include diagrams, charts and illustrations to help students visualize complex concepts in an easier way.

We hope our free Polynuclear Hydrocarbons notes pdf has helped you and please share these Polynuclear Hydrocarbons handwritten notes free pdf with your friends as well 🙏

Download FREE Study Material App for school and college students for FREE high-quality educational resources such as notes, books, tutorials, projects and question papers.

If you have any questions feel free to reach us at tutorialsduniya@gmail.com and we will get back to you at the earliest.

TutorialsDuniya.com wishes you Happy Learning! 🙂

Chemistry Notes

Polynuclear Hydrocarbons Notes FAQs

Q: Where can I get complete Polynuclear Hydrocarbons Notes pdf FREE Download?

A: TutorialsDuniya.com have provided complete Polynuclear Hydrocarbons free Notes pdf so that students can easily download and score good marks in your Polynuclear Hydrocarbons exam.

Q: How to download Polynuclear Hydrocarbons notes pdf?

A: Polynuclear Hydrocarbons students can easily make use of all these complete free Polynuclear Hydrocarbons pdf notes by downloading them from TutorialsDuniya.com